Solute transport within solidifying binary alloys occurs predominantly by convection from narrow liquid chimneys within a porous mushy layer. We develop a simple model that elucidates the dominant structure and driving forces of the flow, which could be applied to modelling brine fluxes from sea ice, where a cheaply implementable approach is essential. A horizontal density gradient within the mushy layer in the vicinity of the chimneys leads to baroclinic torque which sustains the convective flow. In the bulk of the mushy layer, the isotherms are essentially horizontal. In this region, we impose a vertically linear temperature field and immediately find that the flow field is a simple corner flow. We determine the strength of this flow by finding a similarity solution to the governing mushy-layer equations in an active region near the chimney. We also determine the corresponding shape of the chimney, the vertical structure of the solid fraction and the interstitial flow field. We apply this model first to a periodic, planar array of chimneys and show analytically that the solute flux through the chimneys is proportional to a mush Rayleigh number. Secondly we extend the model to three dimensions and find that an array of chimneys can be characterized by the average drainage area alone. Therefore we solve the model in an axisymmetric geometry and find new, sometimes nonlinear, relationships between the solute flux, the Rayleigh number and the other dimensionless parameters of the system.

# Fluxes through steady chimneys in a mushy layer during binary alloy solidification

Peer Reviewed

*Journal of Fluid Mechanics 714*, Issue 0, pages 127-151, 2013, 10.1017/jfm.2012.462.